ASTM A335 P91 (9Cr-1Mo-V): Creep-Strength-Enhanced Ferritic Steel for Power Plants

ASTM A335/A335M · Published: 2026-06-03 · Updated: July 2026

Quick Reference

ASTM A335 P91 (T91 for tube) is a creep-strength-enhanced ferritic (CSEF) steel that revolutionized power plant design — enabling main steam temperatures of 580-620°C at 250-300 bar pressure, dramatically improving thermal efficiency over the P22...

ASTM A335 P91 (T91 for tube) is a creep-strength-enhanced ferritic (CSEF) steel that revolutionized power plant design — enabling main steam temperatures of 580-620°C at 250-300 bar pressure, dramatically improving thermal efficiency over the P22 (2.25Cr-1Mo) steel it replaced. Its 9% chromium, 1% molybdenum, plus microalloying with V, Nb, and N create a stable MX precipitate structure that resists creep for 200,000+ hours at design temperature.

Quick Facts

CategoryAlloy Steel
StandardASTM A335/A335M
Density7.80 g/cm³
Yield Strength415 MPa
Tensile Strength585 MPa

Global Equivalents & Cross-Reference

Alternative Standard / GradeAction
EN X10CrMoVNb9-1 Compare
JIS STPA28 Compare
GB 10Cr9Mo1VNb Compare

Related Materials

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Frequently Asked Questions

What is the post-weld heat treatment requirement for P91?

P91 requires PWHT at 730-760°C for 2 hours minimum (1 hour per 25mm thickness). This is critical: without proper PWHT, the heat-affected zone will have untempered martensite with hardness >400 HV and near-zero toughness — a condition that has caused catastrophic steam pipe failures. PWHT for P91 is NOT optional under any code (ASME B31.1, ASME Section I, EN 13480).

References & International Standards

  • ASTM International. Standard Specifications for Steel & Metal Alloys. astm.org
  • International Organization for Standardization (ISO). Metallic Materials — Cross-Reference Database. iso.org
  • American Iron and Steel Institute (AISI). Steel Grade Designations & Equivalents. steel.org
  • European Committee for Standardization (CEN). EN Steel Standards & Numbering System. cencenelec.eu